# 10820PHYS521000 # 統計力學一 Statistical Mechanics (I) ## Instructor * Prof. Pochung Chen * R521, Physics building * pcchen {at} phys {dot} nthu {dot} edu {dot} tw ## Teaching Assistent * 張宸瑜 * a4201598@gmail.com * General II building, Room-B13 ## Textbooks Main textbook * [Statistical Mechanics: Entropy, Order Parameter, and Complexity](http://pages.physics.cornell.edu/~sethna/StatMech/) by James Sethna. Other references * An introduction to statistical mechanics and thermodynamics by Robert H. Swendsen. ## Time * R5R6R7. ## Room * R019, Physics building. ## Grade (Letter grade) * Exam-1 (35%) * Exam-2 (35%) * Homework (30%) ## YouTube Playlists * [StatMech-I](https://www.youtube.com/playlist?list=PLSZLOtMnuZEURfN0powCIevh2w2jWQ8Nw) ## LMS * [統計力學一Statistical Mechanics (I) ](https://lms.nthu.edu.tw/course/45526) * [How to turn in your homework online](http://sites.powercam.cc/board.php?courseID=157&f=doc&folderID=0&cid=4597) ## Slack * [10820phys521000.slack.com](http://10820phys521000.slack.com) ## Syllabus ### Part-1 * Chapter 1: What is statistical mechanics? * Chapter 3: Temperature and equilibrium * 3.1 The microcanonical ensemble * 3.2 The microcanonical ideal gas * 3.3 What is temperature? * 3.4 Pressure and chemical potential * 3.5 Entropy, the ideal gas, and phase-space refinements * Chapter 2: Random walks and emergent properties * 2.1 Random walk examples: universality and scale invariance * 2.2 The diffusion equation * 2.3 Currents and external forces * 2.4 ~~Solving the diffusion equation~~ * Chapter 5: Entropy * 5.1 Entropy as irreversibility: engines and the heat death of the Universe * 5.2 Entropy as disorder * 5.3 Entropy as ignorance: information and memory * Chapter 6: Free energies * 6.1 The canonical ensemble * 6.2 Uncoupled systems and canonical ensembles * 6.3 Grand canonical ensemble * 6.4 What is thermodynamics? * 6.5 ~~Mechanics: friction and fluctuations~~ * 6.6 ~~Chemical equilibrium and reaction~~ ### Part-2 * Chapter 7: Quantum statistical mechanics * 7.1 Mixed states and density matrices * 7.1.1 Advanced topic: density matrices. * 7.2 Quantum harmonic oscillator * 7.3 Bose and Fermi statistics * 7.4 Non-interacting bosons and fermions * 7.5 Maxwell–Boltzmann ‘quantum’ statistics * 7.6 Black-body radiation and Bose * 7.6.1 Free particles in a box * 7.6.2 Black-body radiation * 7.6.3 Bose condensation * 7.7 Metals and the Fermi gas * Chapter 26: Ideal quantum gases (R. H. Swendsen) * Chapter 27: Bose-Einstein statistics (R. H. Swendsen) * Chapter 28: Fermi-Dirac statistics (R. H. Swendsen) * Chapter 11: Abrupt phase transitions * 11.1 Stable and metastable phases * 11.2 Maxwell construction * Chapter 17: Phase transitions (R. H. Swendsen) * Chapter 12: Continuous phase transitions * Chapter 8: Calculation and model (James Sethna) * Chapter 30: Phase transition and the Ising model (R. H. Swendsen) ## Exams * Exam-1 * 2.1, 2.2, 2.3. * 3.1, 3.2, 3.3, 3.4, ~~3.41~~, 3.5 * 5.1, 5.2, 5.3. * 6.1, 6.2, 6.3, 6.4. * HW1, HW2, HW3, HW4. * Lecture notes. * Exam-2 * James Sethna * Chapter 7.1 to 7.6 * Chapter 11.1, 11.2 * R. H. Swendsen * Chapter 17, 26, 27, 28, 30 ### Weekly schedule * Week 1: 3/5/2020 * Introduction * 3.1 The microcanonical ensemble * 3.2 The microcanonical ideal gas * [Note](https://www.dropbox.com/s/dpdtkeusbo02mub/StatMech_20200305.pdf?dl=0) * Week 2: 3/12/2020 * 3.3 What is temperature? * 3.4 Pressure and chemical potential * 3.5 Entropy, the ideal gas, and phase-space refinements * [Note](https://www.dropbox.com/s/ynwpukw458rbgkq/StatMech_20200312.pdf?dl=0) * Week 3: 3/19/2020 * 3.5 Entropy, the ideal gas, and phase-space refinements * 2.1 Random walk examples: universality and scale invariance * 2.2 The diffusion equation * [Note](https://www.dropbox.com/s/ndf0q215henf7iz/StatMech_20200319.pdf?dl=0) * Week 4: 3/26/2020 [YouTube Live](https://youtu.be/KHi6BaF60LQ) * 5.1 Entropy as irreversibility: engines and the heat death of the Universe. * 5.2 Entropy as disorder. * 5.3 Entropy as ignorance: information and memory. * [Note](https://www.dropbox.com/s/x5zszruuexwed7v/StatMech_20200326.pdf?dl=0) * HW1 due. * Week 5: ~~4/2/2020~~ (No class) * Week 6: 4/9/2020 [YouTube Live](https://youtu.be/_VBNSdmZviA) * 6.1 The canonical ensemble. * 6.2 Uncoupled systems and canonical ensembles. * [Note](https://www.dropbox.com/s/bwy6nv19dun4f2g/StatMech_20200409.pdf?dl=0) * HW2 due. * Week 7: 4/16/2020 [YouTube Live](https://youtu.be/xGiUntNdTMY) * 6.3 Grand canonical ensemble. * 6.4 What is thermodynamics? * [Note](https://www.dropbox.com/s/m0rxi3kr49oin4w/StatMech_20200416.pdf?dl=0) * Week 8: 4/23/2020 [YouTube Live](https://youtu.be/gSddwIAS-p0) * HW3, due. * [Note](https://www.dropbox.com/s/0um91t2pufmpedu/StatMech_20200423.pdf?dl=0) * Week 9: 4/30/2020 [YouTube Live](https://youtu.be/H1VqKfw29-w) * HW4 due. * [Note](https://www.dropbox.com/s/asmm9tfgy4ypv64/StatMech_20200430.pdf?dl=0) * Week 10: 5/7/2020 * **Exam-1** * Week 11: 5/14/2020 * Ideal quantum gases (Swendsen) * [Note](https://www.dropbox.com/s/myysr68m34efigh/StatMech_20200514.pdf?dl=0) * Week 12: 5/21/2020 * HW5 due. * Ideal quantum gases (Swendsen) * Bose-Einstein statistics * [Note](https://www.dropbox.com/s/6okcpturgjghz7b/StatMech_20200521.pdf?dl=0) * Week 13: 5/28/2020 * Fermi-Dirac statistics * [Note](https://www.dropbox.com/s/g5b05yn4aoqtqne/StatMech_20200528.pdf?dl=0) * Week 14: 6/4/2020 * Phase transitions * HW6 due. * [Note](https://www.dropbox.com/s/7p9q4kcjly7e6up/StatMech_20200604.pdf?dl=0) * Week 15: 6/11/2020 * Phase transitions * Week 16: 6/18/2020 * HW7 due. * **Exam-2** ## Homework * HW1, due on 3/26/2020 * Pb 1.4 (v2) Stirling's formula. * Pb 3.6 (v2) Connecting two macroscopic systems. * Pb 3.10 (v2) Triple product relation. * Pb 3.11 (v2) Maxwell relation. * HW2, due on 4/9/2020 * Pb 1.2 (v2) Probability distributions. * Pb 2.1 (v2) Random walks in grade space. * Pb 2.14 (v2) Modified random walk. * Pb 2.15 (v2) Diffusion and conserved particles. * Pb 5.4 (v2) Black hole thermodynamics. * [HW3](http://qubit.phys.nthu.edu.tw/dokuwiki/doku.php?id=10820phys521000-hw3), due on ~~4/16/2020~~ 4/23/2020. * [HW4](http://qubit.phys.nthu.edu.tw/dokuwiki/doku.php?id=10820phys521000-hw4), due on 4/30/2020. * [HW5](http://qubit.phys.nthu.edu.tw/dokuwiki/doku.php?id=10820phys521000-hw5), due on 5/21/2020. * [HW6](http://qubit.phys.nthu.edu.tw/dokuwiki/doku.php?id=10820phys521000-hw6), due on 6/4/2020. * [HW7](http://qubit.phys.nthu.edu.tw/dokuwiki/doku.php?id=10820phys521000-hw7), due on 6/18/2020.